Cu-Catalyzed Three-Component Carboamination of Alkenes

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Gold-catalyzed three-component coupling: oxidative oxyarylation of alkenes.

The three-component coupling of terminal alkenes with arylboronic acids and oxygen nucleophiles is described. The reaction employs a binuclear gold(I) bromide as a catalyst and Selectfluor reagent as the stoichiometric oxidant. Alcohols, carboxylic acids, and water can be employed as oxygen nucleophiles, thus providing an efficient entry into beta-aryl ethers, esters, and alcohols from alkenes.

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Iodine-catalyzed three-component oxysulfenylation of alkenes with sulfonyl hydrazides and alcohols.

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ژورنال

عنوان ژورنال: Journal of the American Chemical Society

سال: 2017

ISSN: 0002-7863,1520-5126

DOI: 10.1021/jacs.7b10529